Overall, the energy of the Earth's magnetic field has been decreasing, so more C is being produced now than in the past.This will make old things look older than they really are.
The isotope concentrations can be measured very accurately, but isotope concentrations are not dates.
To derive ages from such measurements, unprovable assumptions have to be made such as: There is plenty of evidence that the radioisotope dating systems are not the infallible techniques many think, and that they are not measuring millions of years. For example, deeper rocks often tend to give older “ages.” Creationists agree that the deeper rocks are generally older, but not by millions of years.
Geologist John Woodmorappe, in his devastating critique of radioactive dating, points out that there are other large-scale trends in the rocks that have nothing to do with radioactive decay.
Also, the Genesis flood would have greatly upset the carbon balance.
The flood buried a huge amount of carbon, which became coal, oil, etc., lowering the total C ratio in plants/animals/the atmosphere before the flood had to be lower than what it is now.